Qualitative Aspects of Electrolysis Assignment Help
9.9 Qualitative Aspects of Electrolysis
The ability of an ion to get oxidized or reduced depends upon the size, mass, positive charge, negative charge etc. Thus, it is not possible to predict qualitatively that which ion would be discharged first, as one factor might enhance the ability to discharge while the other factor may hamper it. For a cation, the Standard Reduction Potential (SRP) values are compared. The cation having higher standard reduction potential value is discharged in preference to cation with lower SRP value provided the ions are at 1 M concentration. For an anion, the standard oxidation potential (SOP) values are compared and anion having higher SOP is preferentially discharged, if the concentration is 1 M for each of the ion. When solution of an electrolyte contains more than one type of cations and anions at concentrations different from 1 M, the discharge of an ion does not depend solely on standard potentials but also depends on the concentration of ion in the solution. This value is referred as potential, called as reduction potential for cation and oxidation potential for anion. The relation between reduction potential and standard reduction potential is given by Nernst equation, as
where ERP = Reduction potential of cation and Standard reduction potential of cation.
Thus, it is possible that a cation (A+) with lower standard reduction potential getting discharged in preference to cation (B+) having higher standard reduction potential because their concentrations might be such that the reduction potential of A+ is higher than that of B+.
Qualitative Aspects of Electrolysis Assignment Help By Online Tutoring and Guided Sessions at AssignmentHelp.Net
Email Based Assignment Help in Qualitative Aspects of Electrolysis
We are the leading online Assignment Help provider. Find answers to all of your doubts regarding the Qualitative Aspects of Electrolysis in chemistry. We at assignmenthelp.net provide homework, Assignment Help to the school, college or university level students. Our expert online tutors are available to help you in Qualitative Aspects of Electrolysis. Our service is focused on: time delivery, superior quality, creativity and originality.
To Schedule a chemistry Qualitative Aspects of Electrolysis tutoring session
To submit chemistry Qualitative Aspects of Electrolysis assignment click here.