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9.5 Equivalent Conductance
More precisely, equivalent conductivity of a solution at a dilution V may be defined as the conductance of all the ions produced from one gram equivalent of the electrolyte dissolved in V. Equivalent conductivity is represented by l or
Mathematically, l = k × V
k = Specific conductivity or electrolytic conductivity
V = Volume of solutions in c.c. containing 1 gm equivalent of the electrolyte.
Relationship between equivalent and specific conductivities in terms of concentration Suppose the solution has a concentration of c gram equivalent per litre. Then the volume V containing 1 gram equivalent of the electrolyte will be 1/c litre, i.e.
Therefore, the equation becomes
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