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10.10 Radius Ratio

In ionic solid the central cation can touch only that number of anions which should lead to maximum electrostatic attraction and minimum electrostatic repulsion. These interactions depend on size of anion and cation and are greatly influenced by the ratio of radius of the cation and the anion.

Radius ratio <radius ratio

Larger the ratio, greater will be the number of anions in surrounding and greater will be its co-ordination number

Linear void (CN = 2)

Radius ratio for C.N = 2 is less then 0.155 or radius ratio rule

Trigonal planer void (CN = 3)

Let us consider three anions in contact and relatively small cation is present in void. Centre of cation and anions are in the same plane. An equilateral triangle can be constituted by joining centres of anions. Orthocenter of triangle and centre of cation are common. By considering the figure.

radius ratio rules

ionic radius ratio
radius ratio calculation

or anion radius

or cation to anion radius ratio

hence for trigonal planer void

0.155 trigonal planer void radius ratio< 0.225

Tetrahedral void (CN = 4)

Radius ratio for tetrahedral void

0.225tetrahedral void

Square planer (CN = 4)/Octahedral void (CN = 6)

Radius ratio for square planer and octahedral voids

0.414square planer

Cubical void (CN = 8)

Radius ratio for cubical void cubical-void2

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