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Real Gases

The ideal gas laws can be derived from the kinetic theory of gases which is based on the following two important assumptions:

(i) The volume occupied by the molecules is negligible in comparison to the total volume of the gas

(ii) The molecules exert no forces of attraction upon one another.

The molecules in gases also have weak forces of attraction (called van der Waals attraction) amongst themselves; as otherwise, the gases could never be liquefied and solidified.

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