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Asked By :  Arthur Streeton
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Distinguish between saturated and unsaturated fatty acids how

Distinguish between saturated and unsaturated fatty acids. How would a monounsaturated fatty acid compare to a polyunsaturated fatty acid? (Hint: how does structure impact physical properties like melting point)




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Differences Between Saturated and Unsaturated Fatty Acids:

  1. Structure:

    • Saturated Fatty Acids: Contain only single bonds between carbon atoms in the hydrocarbon chain, resulting in a straight, rigid structure.
    • Unsaturated Fatty Acids: Contain one or more double bonds between carbon atoms, introducing kinks in the chain.
  2. Physical State:

    • Saturated Fatty Acids: Typically solid at room temperature (e.g., butter, lard) because the straight chains pack tightly together.
    • Unsaturated Fatty Acids: Typically liquid at room temperature (e.g., olive oil, fish oil) because the kinks prevent tight packing.
  3. Source:

    • Saturated Fatty Acids: Commonly found in animal fats and some tropical oils (e.g., coconut oil).
    • Unsaturated Fatty Acids: Found in plant oils, seeds, and fatty fish.

Monounsaturated vs. Polyunsaturated Fatty Acids:

  1. Double Bonds:

    • Monounsaturated Fatty Acid (MUFA): Contains only one double bond in its hydrocarbon chain (e.g., oleic acid in olive oil).
    • Polyunsaturated Fatty Acid (PUFA): Contains two or more double bonds (e.g., linoleic acid and omega-3 fatty acids in fish oil).
  2. Structure and Kinks:

    • MUFA: Has one kink at the site of the double bond, leading to a slight reduction in packing.
    • PUFA: Has multiple kinks due to multiple double bonds, further reducing the packing ability.
  3. Melting Point:

    • MUFA: Higher melting point than PUFA but lower than saturated fatty acids due to fewer kinks.
    • PUFA: Lower melting point than MUFA because the multiple kinks prevent even more efficient packing, making them more fluid.

In summary, the degree of unsaturation (number of double bonds) significantly affects the fluidity and melting point of fatty acids, with polyunsaturated fatty acids being the most liquid and having the lowest melting point.


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