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the single-pass conversion and reactor balances

The single-pass conversion and reactor balances

Solution

Basis: 100 mol Combined Feed to the Reactor

n5 mol
x4 mol CO2 /mol
3x4 mol H2 /mol
(1-4x4) mol I/mol

n4 mol CO2 /mol
x4 mol CO2 /mol
3x4 mol H2 /mol
(1-4x4) mol I/mol

Take a moment to examine the chart labeling. In particular, notice that we have built in the facts that CO2 and H2 are always present in a 1:3 ratio and that the compositions of the gaseous effluent from the condenser, the purge stream, and the recycle stream are all identical. The more of this sort of information you can incorporate in the chart labeling, the easier the subsequent calculations become. Let us outline the solution, referring to the flowchart.

60% Single-Pass Conversion

n 1 =

.0 400 (

24 5. ) = .9 80 mol CO 2 output =
= 29 4. mol H 2
= 14 7. mol CO 2
n 2

Balances

on CH 3 OH , H 2 O :
= 14 7. mol CH 3

OH

n 3 = 14 7. mol H 2

CO2 Balance About Condenser

n 1 = n 4

x 4

I Balance About Mixing Point

no = 65.4 mol fresh feed
n6 = 34.6 mol recycle

Mole balance About Purge Takeoff

n 4 = n 5 +
[ ( 1000 mol / h ) / n 2 mol ] n 2

= 14 7.

6 .8 03 h

65.4 × 68.06 = 4450 mol fresh feed/h

32

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