Under certain conditions alkanes react with nitric acid, when a hydrogen atom will be placed by a nitro-group, NO2. This process is known as nitration. The mixture consists of all the possible mono nitro-derivatives and nitro-compounds formed by every possibility of chain fission of the alkane. For example, propane gives a mixture of 1-nitropropane, 2-nitropropane, nitroethane and nitromethane.
CH3CH2CH3 CH3CH2CH2NO2 + + C2H5NO2 + CH3NO2
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