Acid is a substance which is capable of furnishing H+ ions in aqueous solution. e.g.-HCl, H2SO4 etc. While base is a substance which furnishes OH– ions. e.g. - NaOH, NH4OH etc.
Limitations: Arrhenius theory failed to explain.
(i) Behaviour of acids/bases in non aqueous solutions.
(ii) Neutralization reaction giving salt in absence of a solvent.
(iii) Acid character of certain salts like AlCl3, BF3 etc.
(iv) Existence of H+ in water.
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