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Alkynes are oxidised by alkaline KMnO4, which causes cleavage of – C  C – resulting in the formation of salts of carboxylic acids. The salts on acidification are converted into acids. Internal alkynes give mixture of carboxylic acids while terminal alkynes give a carboxylic acid and the terminal C-atom is oxidised to CO2 and H2O.

alkynes oxidation

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