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Addition Of Halogens

One or two molecules of halogens can be added to alkynes giving dihalides and tetra halides respectively. Chlorine and bromine add readily to the triple bond while iodine reacts rather slowly.

alkynes halogens

This reaction can be used as a, test to detect unsaturation (both alkenes and alkynes) Br2 in CCl4 is reddish brown in colour while the product obtained is colourless.

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