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Acetylene dimerises when treated with a mixture of Cu2Cl2 and NH4Cl to give vinyl ylene.

alkynes dimerisation

The dimer undergoes addition reactions just like any other unsaturated hydrocarbon addition reaction preferably takes place at the triple bond and not at the double bond inspite of fact that alkynes are less reactive than alkenes towards electrophilic addition reactions, example, addition of HCI to vinyl acetylene gives chloroprene.

alkynes dimerisation

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