Let us consider the ionization of H2S in its aqueous solution. It C is concentration in mole/litre C and Ka1 and Ka2 are ionization constants for first and second step ionization of H2S.
H2S H+ + HS—
C(1-x1) cx1 cx1(1 – y1) (At equilibrium)
HS H+ + S– –
cx1 (1–y1) cx1 y1 x1 y1 (At equilibrium)
because generally hence we can assume that
From equation (i) and (ii) we can calculate the pH of aqueous solution of H2S.
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