Cl2 + H2C = CHCH3 H2C = CHCH2Cl + HCI
Br2 + HH2C = CH – CH3 CH2 = CH – CH2Br + HBr
These halogenations are like free radical substitution of alkanes. The order of reactivity of H-abstraction is allyl > 3° > 2° > 1° vinyl.
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