In any system, a spontaneous process is one which occurs on its own without the help of external energy. The natural changes that occur around us result from such processes. For example, flow of heat from a hot body to a cold one, flow of water downhill, and the expansion of a gas from high pressure to low pressure.
Second law of thermodynamics is concerned with the direction and spontaneity of processes. There are many ways of formulating the law based on our experience of the direction or manner in which natural processes occur. Clausius stated the law as ‘The transference of heat from a cold to a hot body cannot be achieved without the performance of work’.
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