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Nature of Liquid

When the intermolecular forces of attractions are stronger then the vapour pressure will be low because less number of molecules can leave the liquid.

Out of C2H5OH, CH3OCH3, CH3CHO the one with highest vapour pressure is CH3OCH3 and the one with lowest vapour pressure is C2H5OH because in C2H5OH there is hydrogen bonding leading to strongest intermolecular forces where as in CH3OCH3 there is Vander Waals forces leading to weakest intermolecular forces.

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