Let us consider the mixture of aqueous solutions of two weak acids HA1 and HA2 whose concentrations and are C1 and C2 and ionization constants are Ka1 and Ka2.
C1 — —
C1(1 – x1) C1x1 C1x1 (At equilibrium)
HA2 H+ + A2—
C2(1 – x2) C2x2 C2x2 (At equilibrium)
Dividing Eq. 1 by Eq. 2
on putting the value of x1 in terms of x2 in equation (i), we can calculate x2 from above discussion we can calculate the pH of solution mixture of two acids.
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