Some of the lower members of alkyne series can be synthesized by the hydrolysis of carbides. For example, calcium carbide on hydrolysis gives acetylene and magnesium carbide on hydrolysis gives propyne.
CaC2 + 2H2O ® HC = CH + Ca(OH)2
Mg2C3 + 4H2O ® CH3 – C = CH+ 2Mg(OH)2
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