The d-block of the periodic table contains the elements of the groups 3-12 in which the d orbital are progressively filled in each of the four long periods. The elements constituting the f-block are those in which the 4 f and 5 f orbital are progressively filled in the latter two long periods; these elements are formal members of group 3 from which they have been taken out to form a separate f-block of the periodic table. Transition metals and inner transition metals are often used to refer to the elements of d-and f-blocks respectively.
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