The acid catalyzed addition of water to the double bond of an alkene is a method of preparation of low molecular weight alcohols. The addition of water to the double bond follows Markownikov’s rule in those case where rearrangement is not involved.
As the reactions follow Markownikov’s rule acid catalyzed hydration of alkenes do not yield primary alcohols except in the special case of the hydration of ethene. The occurrence of carbocation rearrangements limits the utility of alkene hydrations as a laboratory method for preparing alcohols.
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